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SEMITECH Nano Anatase TiO₂ (<30 nm)

Technical Specifications

ParameterSEMITECH SpecTypical Market RangeTest Method
Crystal phaseAnatase ≥99%Anatase 90–99%XRD (Scherrer)
Primary particle size<30 nm15–50 nmTEM / BET-derived
BET surface area200–300 m²/g100–350 m²/gBET-N₂ (ISO 9277)
TiO₂ purity≥99.5%≥98.0%ICP-OES
pH (5% slurry)6.5–8.05.0–9.0pH meter
Moisture (105°C, 2h)≤0.5 wt%≤1.0 wt%Gravimetric
Surface treatmentSiO₂/Al₂O₃ optionalSiO₂, Al₂O₃, or organicTGA / XPS
UV transmittance (400 nm, 5% dispersion in propylene glycol)≤15%≤25%UV-Vis spectrophotometry

Market Context

Nano-grade anatase occupies a specialty tier distinct from commodity pigment TiO₂. Pigment TiO₂ trades at $2.00–2.80/kg; nano anatase commands $15–50/kg — a premium anchored in synthesis complexity and surface engineering. The specialty nano TiO₂ segment grows at 6–9% CAGR through 2028, driven by UV-protection requirements in personal care, automotive OEM, and architectural glazing.

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Supply Chain

Nano anatase is produced via hydrothermal or flame-hydrolysis routes from TiCl₄ or titanyl sulfate. Australia and South Africa supply ~55% of global ilmenite; China's Panzhihua basin contributes ~30%. TiCl₄ capacity is concentrated in China, creating single-node procurement risk. Surface treatment (SiO₂/Al₂O₃ at 3–8 wt%) adds 20–35% to unit cost. China produces 60–65% of global nano TiO₂, with lead times normalized to 6–10 weeks. MOQs typically run 25–200 kg for qualification, with volume pricing above 500 kg.

Frequently Asked Questions

+Q: Why choose anatase over rutile TiO₂ for UV-blocking in sunscreens?

A: Anatase (band gap 3.2 eV) absorbs slightly more UVB than rutile (3.0 eV), and its lower refractive index (2.55 vs. 2.72) reduces visible whitening in cosmetics.

+Q: What BET surface area is optimal for automotive clear coat formulations?

A: BET 150–250 m²/g. Higher BET (>300 m²/g) raises slurry viscosity and causes haze above 1.5 wt%. Most OEM formulators target 0.8–1.2 wt% at BET 180–220 m²/g.

+Q: What are typical MOQs and lead times from Chinese suppliers?

A: 25–100 kg for qualification trials, 500 kg+ for production. Lead times 4–8 weeks ex-works Shandong. Expect $18–35/kg CIF for surface-treated cosmetic-grade material.

+Q: How does nano anatase TiO₂ pricing respond to raw material fluctuations?

A: Weak correlation with ilmenite spot — raw materials are only 15–25% of production cost. Chinese electricity tariffs are the primary price driver. A 10% electricity rate increase translates to 3–5% nano TiO₂ price increase with 4–8 week lag.

+Q: What regulatory documentation should I request?

A: EU REACH registration number, SDS per Regulation 2015/830, and for cosmetics — compliance with EU Cosmetics Regulation 1223/2009 Annex VI. Particle size by TEM (not DLS alone) is now required under updated SCCS methodology.

+Q: How do I prevent nano anatase agglomeration in sunscreen formulation?

A: Pre-disperse in propylene glycol or cyclopentasiloxane before emulsification. Use high-shear mixing (bead mill 0.3–0.8 mm) with steric dispersant at 10–20 wt% on TiO₂ solids.

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